Photon-Resolved Methods

We build spectrometers and microscopes that record individual photons from the visible into the shortwave infrared.

Interferometry. By sending emitted light through a Mach–Zehnder interferometer and timing each photon, we can record time-resolved spectra from the visible to the SWIR (decay-associated Fourier spectroscopy), and separate emitters by color without filters (spectrally-selective time-resolved emission through Fourier filtering, STEF). We also use photon-correlation Fourier spectroscopy to measure the spectral linewidths of single emitters.

Animation of a Mach–Zehnder interferometer

Counting photons. With superconducting nanowire detectors, we have measured single nanocrystals that emit in the SWIR. Fluorescent optical cycling lets us measure the total photon budget of a molecule: how many photons it emits before it is lost. We have also shown where standard Stern–Volmer and FRET models fail to describe quenching in solution.

Spectroscopy from 2 µm to 400 nm, one photon at a time
Spectroscopy from 2 µm to 400 nm, one photon at a time